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Description of ASTM-D5464 2016ASTM D5464-16Active Standard: Standard Test Method for pH Measurement of Water of Low ConductivityASTM D5464Scope 1.1 This test method is applicable to determine the pH of water samples with a conductivity of 2 to 100 μS/cm over the pH range of 3 to 11 and is frequently used in power generation low conductivity samples. pH measurements of water of low conductivity are problematic. Specifically, this test method avoids contamination of the sample with atmospheric gases and prevents volatile components of the sample from escaping. This test method provides for pH electrodes and apparatus that address additional considerations discussed in Annex A2. This test method also minimizes problems associated with the sample's pH temperature coefficient when the operator uses this test method to calibrate an on-line pH monitor or controller (see Appendix X1). 1.2 This test method covers the measurement of pH in water of low conductivity with a lower limit of 2.0 μS/cm, utilizing a static grab-sample procedure where it is not practicable to take a real-time flowing sample. Note 1: Test Method D5128 for on-line measurement is preferred over this method whenever possible. Test Method D5128 is not subject to the limited conductivity range, temperature interferences, potential KCl contamination, and time limitations found with this method. 1.3 For on-line measurements in water with conductivity of 100 μS/cm and higher, see Test Method D6569. 1.4 For laboratory measurements in water with conductivity of 100 μS/cm and higher, see Test Method D1293. 1.5 The values stated in SI units are to be regarded as standard. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Keywords automatic temperature compensator; controlled leakage rate; flowing liquid junction; high purity water; liquid junction potential; low conductivity water; pH glass electrode; pH temperature coefficient; reference electrode; solution temperature coefficient ; ICS Code ICS Number Code 13.060.50 (Examination of water for chemical substances) DOI: 10.1520/D5464-16 The following editions for this book are also available...This book also exists in the following packages...Subscription InformationMADCAD.com ASTM Standards subscriptions are annual and access is unlimited concurrency based (number of people that can access the subscription at any given time) from single office location. For pricing on multiple office location ASTM Standards Subscriptions, please contact us at info@madcad.com or +1 800.798.9296.
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About ASTMASTM International, formerly known as the American Society for Testing and Materials (ASTM), is a globally recognized leader in the development and delivery of international voluntary consensus standards. Today, some 12,000 ASTM standards are used around the world to improve product quality, enhance safety, facilitate market access and trade, and build consumer confidence. ASTM’s leadership in international standards development is driven by the contributions of its members: more than 30,000 of the world’s top technical experts and business professionals representing 150 countries. Working in an open and transparent process and using ASTM’s advanced electronic infrastructure, ASTM members deliver the test methods, specifications, guides, and practices that support industries and governments worldwide. |
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