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BS EN 71-5:2013 Safety of toys - Chemical toys (sets) other than experimental sets, 2013
- Contents Page
- Foreword
- Introduction
- 1 Scope
- 2 Normative references
- 3 Terms and definitions
- 4 Plaster of Paris (gypsum) moulding sets [Go to Page]
- 4.1 Marking
- 4.2 First aid information
- 4.3 Safety rules
- 5 Ceramic and vitreous enamelling materials supplied in miniature workshop sets [Go to Page]
- 5.1 Chemical mixtures
- 5.2 Marking
- 5.3 First aid information
- 5.4 Safety rules
- 6 Oven-hardening plasticised PVC modelling clay sets [Go to Page]
- 6.1 Chemical substances
- 6.2 Marking
- 6.3 First aid information
- 6.4 Safety rules
- 7 Plastic moulding sets [Go to Page]
- 7.1 Polystyrene granules [Go to Page]
- 7.1.1 Chemical substances
- 7.1.2 Marking
- 7.1.3 First aid information
- 7.1.4 Safety rules
- 7.2 Embedding sets [Go to Page]
- 7.2.1 General
- 7.2.2 Packaging
- 7.2.3 Marking
- 7.2.4 First aid information
- 7.2.5 Safety rules
- 8 Adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) supplied or recommended in model sets [Go to Page]
- 8.1 General
- 8.2 Adhesives [Go to Page]
- 8.2.1 Water-based adhesives [Go to Page]
- 8.2.1.1 General
- 8.2.1.2 Liquid adhesives for paper and wood
- 8.2.1.3 Adhesive sticks for paper
- 8.2.2 Solvent-based adhesives [Go to Page]
- 8.2.2.1 General
- 8.2.2.2 Multi-purpose adhesives
- 8.2.2.3 Contact adhesives
- 8.2.2.4 Special adhesives
- 8.2.2.5 Packaging
- 8.2.2.6 Marking
- 8.2.2.7 First aid information
- 8.2.2.8 Safety rules
- 8.3 Water-based paints and lacquers [Go to Page]
- 8.3.1 General
- 8.3.2 Packaging
- 8.3.3 Marking
- 8.3.4 First aid information
- 8.3.5 Safety rules
- 8.4 Solvent-based paints, lacquers, thinners and cleaning solvents [Go to Page]
- 8.4.1 General
- 8.4.2 Packaging
- 8.4.3 Marking
- 8.4.4 First aid information
- 8.4.5 Safety rules
- 9 Marking [Go to Page]
- 9.1 General
- 9.2 Marking of the primary packaging [Go to Page]
- 9.2.1 General
- 9.2.2 Manufacturer’s identification
- 9.2.3 Warning phrases
- 9.3 Marking of individual containers and any packagings
- 10 Instructions for use [Go to Page]
- 10.1 General
- 10.2 Contents list
- 10.3 Advice for adult supervision
- 10.4 Safety rules
- 10.5 Instructions for carrying out the activities
- 10.6 Spills and disposal of chemicals
- 11 Test methods [Go to Page]
- 11.1 General
- 11.2 Determination of elements in ceramic and vitreous enamelling materials [Go to Page]
- 11.2.1 Principle
- 11.2.2 Standards and reagents [Go to Page]
- 11.2.2.1 Standards
- 11.2.2.2 Reagents
- 11.2.3 Apparatus
- 11.2.4 Preparation of standard solutions [Go to Page]
- 11.2.4.1 Multi-element standard solution I
- 11.2.4.2 Multi-element standard solution II
- 11.2.4.3 Multi-element standard solution III
- 11.2.5 Blank solution
- 11.2.6 Sampling
- 11.2.7 Sample preparation
- 11.2.8 Procedure
- 11.2.9 Evaluation of results [Go to Page]
- 11.2.9.1 General
- 11.2.9.2 Calculation of the pigment contents in the enamel samples
- 11.2.10 Test report
- 11.3 Determination of plasticisers in oven-hardening polyvinyl chloride (PVC) modelling clay sets [Go to Page]
- 11.3.1 Principle
- 11.3.2 Standards and reagents [Go to Page]
- 11.3.2.1 Standards
- 11.3.2.2 Reagents
- 11.3.3 Apparatus
- 11.3.4 Preparation of standard solutions [Go to Page]
- 11.3.4.1 Stock solutions
- 11.3.4.2 Calibration solutions
- 11.3.4.3 Stability of standard solutions
- 11.3.5 Sampling
- 11.3.6 Sample preparation
- 11.3.7 Procedure [Go to Page]
- 11.3.7.1 Extraction of phthalic acid esters, citric acid esters and alkylsulfonic acid esters
- 11.3.7.2 Extraction of adipic acid polyesters
- 11.3.7.3 Evaporation of the solvent and weighing
- 11.3.7.4 Blank determination
- 11.3.7.5 GC-MSD determination of phthalic acid esters, citric acid esters and alkylsulfonic acid esters
- 11.3.7.6 ATR-FT-IR identification of adipic acid polyesters
- 11.3.8 Evaluation of results [Go to Page]
- 11.3.8.1 Calculation of solvent-extractable content containing plasticisers
- 11.3.8.2 Calculation and identification of plasticiser content by GC-MS analysis
- 11.3.9 Test report
- 11.4 Determination of the emission of benzene, toluene and xylenes from oven-hardening plasticised PVC modelling clay sets and plastic moulding sets [Go to Page]
- 11.4.1 Principle
- 11.4.2 Standards and reagents [Go to Page]
- Chemical
- CAS No.
- Toluene
- 108-88-3
- Benzene
- 71-43-2
- o-Xylene
- 95-47-6
- m-Xylene
- 108-38-3
- p-Xylene
- 106-42-3
- Chemical
- CAS No.
- Methanol
- 67-56-1
- 11.4.3 Apparatus
- 11.4.4 Preparation of standard solutions
- 11.4.5 Sampling
- 11.4.6 Sample preparation
- 11.4.7 Procedure
- 11.4.8 Evaluation of results
- 11.4.9 Test report
- 11.4.10 Critical control points
- 11.5 Determination of styrene content in polystyrene granules [Go to Page]
- 11.5.1 Principle
- 11.5.2 Standards and reagents [Go to Page]
- 11.5.2.1 Standards
- 11.5.2.2 Reagents
- 11.5.3 Apparatus
- 11.5.4 Preparation of the standard solutions
- 11.5.5 Sampling
- 11.5.6 Sample preparation
- 11.5.7 Procedure
- 11.5.8 Evaluation of results
- 11.5.9 Test report
- 11.6 Determination of organic solvents [Go to Page]
- 11.6.1 General
- 11.6.2 Principle
- 11.6.3 Standards and reagents [Go to Page]
- 11.6.3.1 Standards
- 11.6.3.2 Reagents
- 11.6.4 Apparatus
- 11.6.5 Preparation of the standard solutions [Go to Page]
- 11.6.5.1 Stock solutions for the identification and determination of solvents using HS-GC-FID
- 11.6.5.2 Stock solutions for the identification and determination of solvents using GC-MS
- 11.6.5.3 Stock solution for the identification and determination of propane-1,2-diol
- 11.6.5.4 Calibration solutions
- 11.6.6 Sampling
- 11.6.7 Sample preparation [Go to Page]
- 11.6.7.1 General
- 11.6.7.2 Sample preparation for identification and determination of solvents by HS-GC-FID
- 11.6.7.3 Sample preparation for identification of solvents by GC-MS
- 11.6.7.4 Sample preparation for determination of certain solvents by GC-MS
- 11.6.7.5 Sample preparation for determination of propane-1,2-diol using GC-FID
- 11.6.8 Procedure [Go to Page]
- 11.6.8.1 Identification of solvents using HS-GC-FID
- 11.6.8.2 Identification of solvents using GC-MS
- 11.6.8.3 Determination of solvent content by HS-GC-FID
- 11.6.8.4 Determination of solvent content using GC-MS
- 11.6.8.5 Determination of propane-1,2-diol by GC-FID
- 11.6.8.6 Blank determination
- 11.6.9 Evaluation of results [Go to Page]
- 11.6.9.1 Calculation of solvent content by HS-GC-FID
- 11.6.9.2 Calculation of solvent content by GC-MS or GC-FID
- 11.6.10 Test report
- 11.7 Combined approach for the determination of plasticisers in solvent-based adhesives and in solvent-based paints and lacquers, film-forming agents in paints and lacquers and modifiers in solvent-based paints and lacquers [Go to Page]
- 11.7.1 Principle
- 11.7.2 Determination of total extract [Go to Page]
- 11.7.2.1 Standards and reagents
- 11.7.2.2 Apparatus
- 11.7.2.3 Sampling
- 11.7.2.4 Sample preparation
- 11.7.2.5 Procedure
- 11.7.2.6 Evaluation of results
- 11.7.3 Identification of nitrocellulose [Go to Page]
- 11.7.3.1 Principle
- 11.7.3.2 Reagents
- 11.7.3.3 Apparatus
- 11.7.3.4 Sampling
- 11.7.3.5 Sample preparation
- 11.7.3.6 Procedure
- 11.7.3.7 Evaluation of results
- 11.7.4 Determination of plasticisers [Go to Page]
- 11.7.4.1 Principle
- 11.7.4.2 Standards and reagents
- 11.7.4.3 Apparatus
- 11.7.4.4 Preparation of the standard solution
- 11.7.4.5 Procedure
- 11.7.4.6 Evaluation of results
- 11.7.5 Determination of film-forming agents [Go to Page]
- 11.7.5.1 Principle
- 11.7.5.2 Standards and reagents
- 11.7.5.3 Apparatus
- 11.7.5.4 Preparation of standard solutions
- 11.7.5.5 Sampling
- 11.7.5.6 Procedure
- 11.7.5.7 Evaluation of results
- 11.7.6 Determination of the modifiers
- 11.7.7 Test report
- Annex A (normative)Environmental, health and safety precautions
- Annex B (informative)Organic solvents
- Annex C (informative)Maximum permitted element concentrations for the compounds permitted in ceramic and vitreous enamelling materials
- Annex D (informative)Validation of test methods
- Annex E (informative)Rationale [Go to Page]
- E.1 General remark
- E.2 Primary packaging (4.1; 5.2; 6.2; 7.1.2; 7.2.2; 8.2.1.2.2; 8.2.2.6; 8.3.2; 8.4.3; 9.2)
- E.3 Minimum age (4.1; 5.2; 6.2; 7.1.2; 7.2.3; 8.2.1.2.3; 8.2.1.3.3; 8.2.2.6; 8.3.3; 8.4.3)
- E.4 Phthalates (6.1 Table 2; 8.2.2; 8.4.1)
- E.5 Benzene (6.1, Table 3; 8.2.2.4, Table 12; 8.4.1, Table 16)
- E.6 Preservatives (7.2.1; 8.2.1.1; 8.3.1)
- Annex F (informative)Significant technical changes between this European Standard and the previous version
- Annex ZA (informative)Relationship between this European Standard and the Essential Requirements of EU Directive 2009/48/EC
- Bibliography [Go to Page]