Significance and Use

This test method is a relative measure of the degree of oxidation present in coal. It does not determine the quantitative amount of oxidized coal present. It is only intended to serve as a guide to the supplier, buyer, and user for selecting coals for metallurgical use.

Note 1The values shown in Table 1 are based on the transmittance obtained using the original procedure (wavelength at 520 nm, 17-mm light path, 2 to 3-min boiling time, dilution of the extract to 80 mL). At these conditions, coals that had transmittance values greater than 90 % were considered to be unoxidized, coals less than 80 % were considered to be oxidized, and coals between 80 and 90 % were considered suspect. As this procedure becomes accepted as the standard and more experimental data are gathered, modifications to these cutoff values are expected. Note that lower rank bituminous coals are more easily extracted than higher rank coal.

1. Scope

1.1 This colorimetric test method describes the determination of the relative degree of oxidation by alkali extraction of coals that are high volatile A bituminous to low volatile bituminous in rank.

1.2 This test cannot be sensitive to thermally oxidized coal. It is intended for coals that may be oxidized as a result of weathering.

1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

1.4 The values stated in SI units shall be regarded as standard.

2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

ASTM Standards

D1193 Specification for Reagent Water

D4621 Guide for Quality Management in an Organization That Samples or Tests Coal and Coke

Keywords

absorbance; alkali extraction; colorimetric; humic acids; oxidation (weathering); transmittance; Humic acids; Absorbance and transmittance; Alkali extraction; Colorimetric analysis; Extraction methods; Oxidation testing; Transmittance and reflectance; Weathering;

ICS Code

ICS Number Code 73.040 (Coals)

DOI: 10.1520/D5263-93R08E01

ASTM International is a member of CrossRef.

ASTM D5263