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  • ASTM
    D6378-18 Standard Test Method for Determination of Vapor Pressure (VPX) of Petroleum Products, Hydrocarbons, and Hydrocarbon-Oxygenate Mixtures (Triple Expansion Method)
    Edition: 2018
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    Unlimited Users per year

Description of ASTM-D6378 2018

ASTM D6378-18

Historical Standard: Standard Test Method for Determination of Vapor Pressure (VPX) of Petroleum Products, Hydrocarbons, and Hydrocarbon-Oxygenate Mixtures (Triple Expansion Method)




ASTM D6378

Scope

1.1 This test method covers the use of automated vapor pressure instruments to determine the vapor pressure exerted in vacuum by volatile, liquid petroleum products, hydrocarbons, and hydrocarbon-oxygenate mixtures including ethanol blends up to 85 % (volume fraction). This test method is suitable for testing samples with boiling points above 0 °C (32 °F) that exert a vapor pressure between 7 kPa and 150 kPa (1.0 psi and 21 psi) at 37.8 °C (100 °F) at a vapor-to-liquid ratio of 4:1. The liquid sample volume size required for analysis is dependent upon the vapor-to-liquid ratio chosen (see Note 1) and the measuring chamber volume capacity of the instrument (see 6.1.1 and Note 5).

Note 1: The test method is suitable for the determination of the vapor pressure of volatile, liquid petroleum products at temperatures from 0 °C to 100 °C at vapor to liquid ratios of 4:1 to 1:1 (X = 4 to 1) and pressures up to 500 kPa (70 psi), but the precision statement (see Section 16) may not be applicable.

Note 2: The precision (see Section 16) using 1 L containers was determined in a 2003 interlaboratory study (ILS);2 the precision using 250 mL containers was determined in a 2016 ILS.3

1.2 This test method also covers the use of automated vapor pressure instruments to determine the vapor pressure exerted in vacuum by aviation turbine fuels. This test method is suitable for testing aviation turbine fuel samples with boiling points above 0 °C (32 °F) that exert a vapor pressure between 0 kPa and 110 kPa (0 psi and 15.5 psi) at a vapor-to-liquid ratio of 4:1, in the temperature range from 25 °C to 100 °C (77 °F to 212 °F).

Note 3: The precision (see Section 16) for aviation turbine fuels using 100 mL containers was determined in a 2007 ILS.4

1.3 The vapor pressure (VPX) determined by this test method at a vapor-liquid ratio of 4:1 (X = 4) of gasoline and gasoline-oxygenate blends at 37.8 °C can be correlated to the dry vapor pressure equivalent (DVPE) value determined by Test Method D5191 (see 16.3). This condition does not apply when the sample is aviation turbine fuel.

1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see 7.2 – 7.8.

1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.


Keywords

aviation turbine fuel; dry vapor pressure; gasoline; gasoline and gasoline-oxygenate blends; hydrocarbon-oxygenate blends; mini method; petroleum products; vapor pressure; variable volume method;


ICS Code

ICS Number Code 75.080 (Petroleum products in general)


DOI: 10.1520/D6378-18

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ASTM International, formerly known as the American Society for Testing and Materials (ASTM), is a globally recognized leader in the development and delivery of international voluntary consensus standards. Today, some 12,000 ASTM standards are used around the world to improve product quality, enhance safety, facilitate market access and trade, and build consumer confidence. ASTM’s leadership in international standards development is driven by the contributions of its members: more than 30,000 of the world’s top technical experts and business professionals representing 150 countries. Working in an open and transparent process and using ASTM’s advanced electronic infrastructure, ASTM members deliver the test methods, specifications, guides, and practices that support industries and governments worldwide.

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