ASTM D6591

Scope

1.1 This test method covers a high performance liquid chromatographic test method for the determination of mono-aromatic, di-aromatic, tri+-aromatic, and polycyclic aromatic hydrocarbon contents in diesel fuels and petroleum distillates boiling in the range from 150 to 400°C. The total aromatic content in % m/m is calculated from the sum of the corresponding individual aromatic hydrocarbon types.

Note 1—Aviation fuels and petroleum distillates with a boiling point range from 50 to 300°C are not determined by this test method and should be analyzed by Test Method, D6379 or other suitable equivalent test methods.

1.2 The precision of this test method has been established for diesel fuels and their blending components, containing from 4 to 40 % (m/m) mono-aromatic hydrocarbons, 0 to 20 % (m/m) di-aromatic hydrocarbons, 0 to 6 % (m/m) tri+-aromatic hydrocarbons, 0 to 26 % (m/m) polycyclic aromatic hydrocarbons, and 4 to 65 % (m/m) total aromatic hydrocarbons.

1.3 Compounds containing sulfur, nitrogen, and oxygen are possible interferents. Mono-alkenes do not interfere, but conjugated di- and poly-alkenes, if present, are possible interferents.

1.4 By convention, this standard defines the aromatic hydrocarbon types on the basis of their elution characteristics from the specified liquid chromatography column relative to model aromatic compounds. Quantification is by external calibration using a single aromatic compound, which may or may not be representative of the aromatics in the sample, for each aromatic hydrocarbon type. Alternative techniques and methods may classify and quantify individual aromatic hydrocarbon types differently.

1.5 Fatty Acid Methyl Esters (FAME), if present, interfere with tri+-aromatic hydrocarbons. If this method is used for diesel containing FAME, the amount of tri+-aromatics will be over estimated.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Keywords

aromatic hydrocarbons; aromatics; diesel fuel; high performance liquid chromatography; hydrocarbon types; petroleum distillates; refractive index detection; total aromatics in fuel; Total aromatics in fuel; Aromatic hydrocarbons (AHs); Diesel engine fuel oils; HPLC (high performance liquid chromatography); Hydrocarbons; Petroleum distillates; Refractive index

ICS Code

ICS Number Code 71.040.50 (Physicochemical methods of analysis)

DOI: 10.1520/D6591-11