ASTM D7057-09
Historical Standard: ASTM D7057-09 Standard Test Method for Analysis of Isopropylbenzene (Cumene) by Gas Chromatography (External Standard)
SUPERSEDED (see Active link, below)
ASTM D7057
1. Scope
1.1 This test method covers the determination of the purity of isopropylbenzene (cumene) by gas chromatography. Calibration of the gas chromatography system is done by the external standard calibration technique.
1.2 This test method has been found applicable to the measurement of impurities such as nonaromatic hydrocarbons, benzene, toluene, ethylbenzene, phenol, cymenes, t -butylbenzene, n -butylbenzene, n -propylbenzene, alpha -methylstyrene, sec -butylbenzene, and diisopropylbenzenes, which are impurities that can be found in isopropylbenzene. The latter impurities can be analyzed over a range of 1 mg/kg to 500 mg/kg by this method (see Table 1). The limit of detection for these impurities is summarized in Table 1 as well.
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E 29 .
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.
TABLE 1 Summary of Precision Data (mg/kg)
| Compound | Repeatability | Reproducibility |
Range Studied |
|---|---|---|---|
| Benzene | 1.004+0.006*Benzene | 0.924+0.158*Benzene | 1.0 295 |
| Toluene | 0.644+0.009*Toluene | 1.505+0.069*Toluene | 0.2 260 |
| Ethylbenzene (EB) | 1.249+0.022*EB | 2.534+0.230*EB | 5 370 |
| n- Propylbenzene (NPB) | -0.369+0.015*NPB | -6.793+0.214*NPB | 180 465 |
| Phenol (PHE) | 1.926+.0095*PHE | 3.718+0.207*PHE | 1 225 |
| alpha- methylstyrene(AMS) | 1.368+0.057*AMS | 21.181+0.976*AMS | 6 305 |
| tert- Butylbenzene(TBB) | 1.666+0.011*TBB | 4.126+0.086*TBB | 2 250 |
| sec- Butylbenzene(SBB) | 0.635+0.010*SBB | 0.891+0.090*SBB | 2 245 |
| m- Cymene | 0.618+0.011* m- Cymene | 1.811+0.181* m- Cymene | 5 240 |
| o- Cymene | 0.498+0.012* o- Cymene | 1.951+0.156* o- Cymene | 1 160 |
| p- Cymene | 0.485+0.019* p- Cymene | 1.618+0.097* p- Cymene | 2 270 |
| n- Butylbenzene(NBB) | 0.445+0.030*NBB | 2.600+0.045*NBB | 0.3 265 |
| 1,3-diisopropylbenzene(13DIPB) | 0.727+0.010*13DIPB | 1.570+0.720*13DIPB | 1 210 |
| 1,4-diisopropylbenzene(14DIPB) | 0.435+0.013*14DIPB | 1.112+0.040*14DIPB | 1 285 |
| NonAromatics(NA) | 0.441+0.242*NA | 1.663+0.306*NA | 5 95 |
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
ASTM Standards
D3437 Practice for Sampling and Handling Liquid Cyclic Products
D4307 Practice for Preparation of Liquid Blends for Use as Analytical Standards
D4790 Terminology of Aromatic Hydrocarbons and Related Chemicals
D6809 Guide for Quality Control and Quality Assurance Procedures for Aromatic Hydrocarbons and Related Materials
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
E355 Practice for Gas Chromatography Terms and Relationships
E691 Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
E1510 Practice for Installing Fused Silica Open Tubular Capillary Columns in Gas Chromatographs
Keywords
alpha- methylstyrene; analysis by gas chromatography; benzene; butylbenzene; cumene; cymene; diisopropylbenzene; ethylbenzene; isopropylbenzene; methyl cumene; nonaromatic hydrocarbons; propylbenzene; toluene;
ICS Code
ICS Number Code 71.080.15 (Aromatic hydrocarbons)
DOI: 10.1520/D7057-09
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