1. Scope

1.1 This test method covers a direct injection ion chromatographic procedure for determining existent and potential inorganic sulfate and total inorganic chloride content in hydrous and anhydrous denatured ethanol to be used in motor fuel applications. It is intended for the analysis of ethanol samples containing between 1.0 20 mg/kg of existent or potential inorganic sulfate and 1.0 50 mg/kg of inorganic chloride.

1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Material Safety Data Sheets are available for reagents and materials. Review them for hazards prior to usage.

2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

ASTM Standards

D1193 Specification for Reagent Water

D4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter

D4057 Practice for Manual Sampling of Petroleum and Petroleum Products

D4177 Practice for Automatic Sampling of Petroleum and Petroleum Products

D5827 Test Method for Analysis of Engine Coolant for Chloride and Other Anions by Ion Chromatography

D6299 Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance

D6792 Practice for Quality System in Petroleum Products and Lubricants Testing Laboratories

D7318 Test Method for Existent Inorganic Sulfate in Ethanol by Potentiometric Titration

D7328 Test Method for Determination of Existent and Potential Inorganic Sulfate and Total Inorganic Chloride in Fuel Ethanol by Ion Chromatography Using Aqueous Sample Injection

Keywords

anions; chloride; direct injection; ethanol; existent inorganic sulfate; inorganic chloride; potential sulfate; sulfate; suppressed ion chromatography; total chloride;

ICS Code

ICS Number Code 71.040.50 (Physicochemical methods of analysis); 75.160.20 (Liquid fuels)

DOI: 10.1520/D7319-11E01

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