Significance and Use

This test method is used for the determination of phosphorus in nickel, ferronickel, and nickel alloy samples by molecular absorption spectrometry to check compliance with compositional specifications. It is assumed that all who use the procedure will be trained analysts capable of performing common laboratory procedures skillfully and safely. It is expected that the work will be performed in a properly equipped laboratory and that proper waste disposal procedures will be followed. Appropriate quality control practices must be followed, such as those described in Guide E 882 .

1. Scope

1.1 This test method covers the determination of phosphorus in nickel, ferronickel, and nickel alloys in the range 0.0007 % to 0.05 %.

1.2 Arsenic, chromium, hafnium, niobium, silicon, tantalum, titanium, and tungsten interfere, but the interference can be avoided by complexation or volatilization (for chromium). The lowest phosphorus content (0.0007 %) can be reached only in samples with low contents of interfering elements.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazards associated with the use of this test method see Practices E 50 . Refer to specific warning notes given throughout this test method.

2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

ISO Standards

ASTM Standards

E50 Practices for Apparatus, Reagents, and Safety Considerations for Chemical Analysis of Metals, Ores, and Related Materials

E135 Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials

E882 Guide for Accountability and Quality Control in the Chemical Analysis Laboratory

E1601 Practice for Conducting an Interlaboratory Study to Evaluate the Performance of an Analytical Method

Keywords

ferronickel; molecular absorption spectrometry; nickel; nickel alloy; phosphorus content; spectrophotometric; Phosphorus content--metals/alloys; Chemical spot test; Ferronickel; Nickel; Nickel alloys; Phosphovanadomolybdate molecular absorption spectrometry; Spectrometry; Spectroscopy; Thermoelectric method;

ICS Code

ICS Number Code 77.120.40 (Nickel, chromium and their alloys)

DOI: 10.1520/E1917-08

ASTM International is a member of CrossRef.

ASTM E1917